Effect of fluid concentration in titanium machining with an atomization-based cutting fluid (ACF) spray system

The aim of this work is to investigate the effect of metal-working fluid (MWF) concentration on the machining responses including tool life and wear, cutting force, friction coefficient, chip morphology, and surface roughness during the machining of titanium with the use of the ACF spray system. Five different concentrations from 5 to 15% of a water-soluble metalworking fluid (MWF) were applied during turning of a titanium alloy, Ti–6Al–4V. The thermo-physical properties such as viscosity, surface tension and thermal conductivity of these concentrations were also measured. The test results demonstrate that the tool life first extends with the increase in MWF concentration and then drops with further increase. At low concentration (e.g., 5%), a lack of the lubrication effect causes to increase in a higher friction at the tool–chip interface resulting in severe chipping and tool nose/flank wear within a short machining time. On the other hand, at high concentration, the cooling effect is less. This increases cutting temperature and a faster thermal softening/chipping/notching of the tool material and higher friction at the tool–chip–workpiece interaction zones resulting in early tool failure. A good balance between the cooling and the lubrication effects seems to be found at the 10% MWF concentration as it offers the best machining performance. However, machining with flood coolant is observed to perform the best in the range of 5–7%.     

Temporal signatures of advective versus diffusive radon transport at a geothermal zone in Central Nepal

Temporal variation of radon-222 concentration was studied at the Syabru-Bensi hot springs, located on the Main Central Thrust zone in Central Nepal. This site is characterized by several carbon dioxide discharges having maximum fluxes larger than 10 kg m⁻² d⁻¹. Radon concentration was monitored with autonomous Barasol™ probes between January 2008 and November 2009 in two small natural cavities with high CO₂ concentration and at six locations in the soil: four points having a high flux, and two background reference points. At the reference points, dominated by radon diffusion, radon concentration was stable from January to May, with mean values of 22 ± 6.9 and 37 ± 5.5 kBq m⁻³, but was affected by a large increase, of about a factor of 2 and 1.6, respectively, during the monsoon season from June to September. At the points dominated by CO₂ advection, by contrast, radon concentration showed higher mean values 39.0 ± 2.6 to 78 ± 1.4 kBq m⁻³, remarkably stable throughout the year with small long-term variation, including a possible modulation of period around 6 months. A significant difference between the diffusion dominated reference points and the advection-dominated points also emerged when studying the diurnal S₁ and semi-diurnal S₂ periodic components. At the advection-dominated points, radon concentration did not exhibit S₁ or S₂ components. At the reference points, however, the S₂ component, associated with barometric tide, could be identified during the dry season, but only when the probe was installed at shallow depth. The S₁ component, associated with thermal and possibly barometric diurnal forcing, was systematically observed, especially during monsoon season. The remarkable short-term and long-term temporal stability of the radon concentration at the advection-dominated points, which suggests a strong pressure source at depth, may be an important asset to detect possible temporal variations associated with the seismic cycle.     

Geochemistry of high arsenic groundwater in Chia-Nan plain, Southwestern Taiwan: possible sources and reactive transport of arsenic

Major ion, trace element, and stable isotope analyses were performed on groundwater samples collected during November 2005 and 2006 in Chia-Nan plain of southwestern Taiwan to examine As mobilization in aquifers. The high concentrations of As, Fe and Mn in the groundwater is consistent with low Eh values (under moderately reduced state). Moreover, the observed Na/Cl and SO(4)/Cl molar ratios in groundwater demonstrate the influence of seawater intrusion. Seawater intrusion could provide required electron acceptors (i.e., SO(4)) for bacterial sulfate reduction and promote reducing conditions that are favorable for As mobilization. The concurrent increases in the concentrations of Fe and Mn from 2005 to 2006 may be caused by bacterial Fe(III) and Mn(IV) reduction. Geochemical modeling demonstrate that As(III) is the dominant As species and the presence of Fe-bearing carbonates, sulfides, and oxide phases may locally act as potential sinks for As. Mud volcano fluids were also collected and analyzed to assess the possible source of As in the Chia-Nan plain groundwater. The oxygen and hydrogen isotopic signatures indicate that the As-rich mud volcano fluids may have been modified by chemical exchange with (18)O-rich crustal rocks and possibly originated from mixing of deep brines with circulating meteoric water. Thus As in the Chia-Nan plain groundwater may have been evolved from deep crustal fluids or rock sources. The hydrogeochemistry and widespread As enrichment in groundwater of Chia-Nan plain result from multiple processes, e.g., de-watering of deep crustal fluids, seawater intrusion, and biogeochemical cycling of Fe, As, and S in alluvial sediments.     

The application of zero-water discharge system in treating diffuse village wastewater and its benefits in community afforestation

The proposed on-site zero-water discharge system was comprised of four main components: anaerobic tank, aerobic bioreactor, activated soil filter and water-collecting well. The results demonstrate that at 350 m³ day⁻¹ of hydraulic load, the system can effectively remove pollutants from the wastewater, e.g., 86% removal of COD; 87% removal of SS; 80% removal of TP and 71% removal of TN. The growth states of the grasses, macrophytes and arbors in the activated soil filter were better than the control. The life of the activated soil filter was estimated to be ∼12-15 yrs, based on the laboratory microcosm studies. However, humic acid contents and soil porosity have suggested that the activated soil filter was able to regenerate itself and thereby prolonging its life by reducing clogging of the pores. The results suggest that the zero-water discharge system was a promising bio-measure in treating diffuse village wastewater and benefiting community afforestation.     

The cost of water

Summary For all too many developing countries, it is a case of “Water, water everywhere and not a drop to drink”. In many of the Least Developed Countries, safe drinking water and excreta disposal facilities are sadly inadequate. Published by kind permission ofWorld Health, WHO, Geneva, Switzerland. Miss Uma Ram Nath is a freelance journalist from New Delhi, India, writing on Third World development themes.     

Physicochemical methods for monitoring seasonal variations in Cl–, F–, and Fe++ in underground water in Unnao District in Uttar Pradesh (India)

The variations of Cl^???, F^???, and Fe^?+?+? in the underground water during pre- and post-monsoon periods for 2003 have been examined, for two places in Unnao district, by argentrometric titration method (Sodic Land Reclamation Project Uttar Pradesh 1998) and atomic absorption spectrometry (Sodic Land Reclamation Project Uttar Pradesh 1998). The concentration of these ions falls outside the limits prescribed by the World Health Organization (WHO 1984).     

Evaluation of the individuality of white rot macro fungus for the decolorization of synthetic dye

Introduction

A biosorbent was developed by simple dried Agaricus bisporus (SDAB) and effectively used for the biosorption of cationic dyes, Crystal Violet and Brilliant Green.

Materials and methods

For the evaluation of the biosorbent system, all the batch equilibrium parameters like pH, biomass dose, contact time, and temperature were optimized to determine the decolorization efficiency of the biosorbent. The maximum yields of dye removal were achieved at pH 4.0 for Crystal Violet (CV) and pH 5.0 for Brilliant Green (BG), which are closer to their natural pH also.

Result and discussion

Equilibrium was established at 60 and 40 min for CV and BG, respectively. Pseudo first-order, pseudo second-order, and intraparticle-diffusion kinetic models were studied at different temperatures. Isotherm models such as Freundlich, Langmuir, and Dubinin–Radushkevich were also studied. Biosorption processes were successfully described by Langmuir isotherm model and the pseudo second-order kinetic model.

Conclusions

The biosorption capacity of A. bisporus over CV and BG were found as 21.74 and 12.16 mg gm^?1. Thermodynamic parameters indicated that the CV and BG dye adsorption onto A. bisporus is spontaneous and exothermic in the single and ternary systems. Scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy were used for the surface morphology, crystalline structure of biosorbent, and dye–biosorbent interaction, respectively. This analysis of the biosorption data confirmed that these biosorption processes are ecofriendly and economical. Thus, this biomass system may be useful for the removal of contaminating cationic dyes.     

Hydrogeochemical behavior of arsenic-enriched groundwater in the deltaic environment: comparison between two study sites in West Bengal, India

Groundwaters have been collected from deltaic areas of West Bengal (Chakdaha and Baruipur blocks) to record their hydrogeochemical characteristics, and to verify the mechanism of arsenic (As) release. The data reveals that shallow (<70 m) groundwaters in both areas are of Ca-Mg-HCO(3) type; however deeper (>70 m) groundwaters in Baruipur areas are slightly enriched with Na, Cl and SO(4), indicating possible saline water intrusion. The groundwater is anoxic (mean Eh: -124 and -131 mV) with high levels of As (mean: 116 and 293 mug/L), Fe (mean: 4.74 and 3.83 mg/L), PO(4) (mean: 3.73 and 3.21 mg/L) and Mn (mean: 0.37 and 0.49 mg/L), respectively for Chakdaha and Baruipur areas. The observed values of As and bicarbonate (mean: 409 and 499 mg/L) in the shallow aquifer are indicative of redox processes (e.g., oxidation of organic matter) favouring the release of As. Moreover, the presence of DOC in the shallow aquifer suggests that organic matter is young and reactive, and may actively engage in redox driven processes. Our study further confirms that both Fe- and Mn-reduction processes are the dominant mechanisms for As release in these groundwaters.     

Association between skin lesion and arsenic concentration in hair by mixed bivariate model in chronic arsenic exposure

Skin lesion is one of the important health hazards caused by high intake of arsenic through drinking water and diet, and the other hazards include several types of cancers (viz. skin, lung and urinary bladder), ischemic heart disease, hypertension, etc. Two most important biomarkers to measure arsenic intake in a human body are arsenic concentration in urine and hair. The primary interest of this paper is the association between skin lesion and arsenic concentration in hair for participants with chronic arsenic exposure from West Bengal, India, using bivariate regression model based on copula function. The result showed participants with high arsenic concentration in hair had higher incidence of developing skin lesion. Arsenic concentration in hair was significantly higher for the participants with an arsenic concentration in water?>?10 mg/L.     

The Johannesburg Conference

The World Summit on Sustainable Development (WSSD), held in Johannesburg during 26 August and 4 September 2002, was the biggest event of its kind organised by the United Nations to date. A major objective of the WSSD was to set out strategies for greater and more effective implementation of Agenda 21, negotiated in Rio ten years ago, than hitherto. An overview of the WSSD is presented in this chapter, including a scrutiny of its major outcomes.Discussion begins with a detailed account of major UN environmental conferences and related events, such as Doha and Monterrey conferences, that led to the WSSD, followed by a brief discussion of the deliberations that took place at the preparatory meetings (PrepComs) of the WSSD. A detailed account and scrutiny of the following, that are the main outcomes of the WSSD, is then given.The "Johannesburg Declaration on Sustainable Development", which is a political declaration mirroring the will of the international community to move towards sustainable development.The "Johannesburg Plan of Implementation", which is the core document of the WSSD containing an impressive list of recommendations for accelerating the implementation of Agenda 21."Type II partnerships", which are projects that allow civil society to contribute to the implementation of sustainable development.The increasingly important post-Rio issue of globalisation, which has serious implications for a number of issues directly or indirectly impinging on global sustainability, was an important element in the contextual background to the WSSD. Reference is made to some of these implications.Type II partnerships are an innovation of the WSSD. Although a good deal of confusion persists over their precise nature and modus operandi, they were nevertheless presented at the WSSD as powerful and more democratic instruments for the realisation of Agenda 21 objectives.The analysis shows that the Summit contributed at defining sustainable development more precisely. The Plan of Implementation is most instrumental in showing how to make resource use and the generation of pollution less unsustainable. In this way implementing the recommendations of the Johannesburg Summit offers an important defeat, worldwide.